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>So you claim that the rate of the enzyme reaction
>> A + B + E ->
>>cannot be described by
>> V+ = K+(E)(A)
>>Utter nonsense? Lukasz, what are you talking about?
on can not plug in blindly whatever eqution seems convenient.
under certain conditions using this equation is ok to describe the
rate of _the enzyme reaction_. But in general it describes only the rate
of _the first step_. If close to equilibrium one needs more than that.
if you want to prove anything solve the complete set of equations with
no arbitrary oversimplifications. otherwise give yourself a break.
lukasz
