what is "sokkrplarluvsH20"
Wolfgang Schechinger
wolfsc at ibms.sinica.edu.tw
Tue Feb 20 21:33:12 EST 2001
> Subject: Re: what is "sokkrplarluvsH20"
Answer: A very interesting nobel gas complex, containing an
argon-krypton gas hydrate center.
Ffirst described in investigation of a disastrous explosion of a
confocal laser scanning microscope laser unit
(Ref.: A. Big, N. Bang-Bumm, J. Catast.Res.Chem 112, 110 (2000)).
and recently syntesized from the elements in a argon/mud matrix at
-293 deg C by atomic waste ion beaming .
(Ref.: M. Quark-Strudel, A. Big, N. Bang-Bumm, New Int. J. Hyperlow
Temp. Chem. 273, 27 (2001))
Exact formula of this complex is (SO4K)42-Ar=Kr(H2O)42-(PI2[UV5S])42
It was the first observation of a Ar=Kr double bond of which the
exact nature still remains to be elucidated. Spectroscopical
experiments gave hint to the existence of two spin uncupled single
electron reverse bonds. The high resonance energy of this bond is
stabilized by 42 units of the phosphorous-heavy metal complex
PI2[UV5S] that shields the molecule completely. The potassium
and sulfate ions are necessary for charge compensation. 42 water
molecules are buried within the whole structure and were detected by
Karl-Fischer titration.
HTH
Wolfgang
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Dr. Wolfgang Schechinger
Institute of Biomedical Sciences
Academia Sinica
Taipei 115
Taiwan R.O.C.
Tel +886-2-2798-9152
Fax +886-2-2782-9142
wolfsc at ibms.sinica.edu.tw
http://wofo.50g.com
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